If Grohk uses Spirit's Domain, his lightning doesn't hit through allies, but his Shock Pulse does. He may try to stay in the front if they group to get some damage in, so use that opportunity to burst him down.
Shock Pulse will bounce if it hits a deployable like Ying's Illusions or Barik's Turrets. If you are playing competitive and he is picked early, avoid using these two to make Shock Pulse more difficult to use.